|
|
|
| A Comparative Study of NSO Compounds in High Thermal Maturity Shale from South China Based on Electrospray Ionization Coupled with Fourier Transform Ion Cyclotron Resonance Mass Spectrometry |
| KE Chang-wei, XU Yao-hui |
| College of Resources and Environment, Yangtze University, Key Laboratory of Exploration Technologies for Oil and Gas Resources, Ministry of Education, Wuhan 430100, China |
|
|
|
|
Abstract This research uses a Fourier transform ion cyclotron resonance mass spectrometry (ESI FT-ICR MS) combined with gas chromatography to compare the NSO compounds in the Sinian Doushantuo Formation in western Hubei province and the Longmaxi Formation in the Sichuan Basin. The study of organic heteroatomic types have shown that nitrogen compounds were absent in these two formations, and the DBE (Double Bond Equivalence) values were lower because the rocks are high maturity. The Sinian Doushantuo Formation contains high O3 compounds, while the Longmaxi Formation is mainly composed by O2 compounds. The Sinian Doushantuo Formation was formed from relative occlusion of with a certain amount of evaporation, whereas sedimentary environment of the Longmaxi formation is relatively open, resulting in higher O3S heteroatom compounds in the Sinian Doushantuo Formation than the Longmaxi Formation. Due to exposure to surface, the Longmaxi Formation might have been degraded by microorganisms, containing much higher heteroatom compounds content than the Sinian Doushantuo Formation.
|
|
Received: 28 July 2017
|
|
|
|
|
李辉. 2013. 川东南下古生界烃源岩特征研究. 硕士学位论文. 成都:成都理工大学
|
|
李素梅, 孟祥兵, 张宝收, 张海祖, 潘娜, 史权. 2013b. 傅里叶变换离子回旋共振质谱的地球化学意义及其在油气勘探中的应用前景. 现代地质, 27(1):124-132
|
|
张旋. 2013. 鄂西地区及其邻区下震旦统陡山沱组黑色页岩特征研究. 硕士学位论文. 成都:成都理工大学
|
|
周爱徽. 2011. 塔河常压渣油中钒化合物的分离、提纯与鉴定. 硕士学位论文. 青岛:中国石油大学(华东)
|
|
Hughey C A, Rodgers R P, Marshall A G, Walters C C, Qian K N, Mankiewicz P. 2004. Acidic and neutral polar NSO compounds in Smackover oils of different thermal maturity revealed by electrospray high field Fourier transform ion cyclotron resonance mass spectrometry. Organic Geochemistry, 35(7):863-880
|
|
Kim S, Stanford L A, Rodgers R P, Marshall A G, Walters C C, Qian K N, Wenger L M, Mankiewicz P. 2005. Microbial alteration of the acidic and neutral polar NSO compounds revealed by Fourier transform ion cyclotron resonance mass spectrometry. Organic Geochemistry, 36(8):1117-1134
|
|
Li S M, Pang X Q, Shi Q, Zhang B S, Zhang H Z, Pan N, Zhao M. 2011. Origin of the unusually high dibenzothiophene concentrations in Lower Ordovician oils from the Tazhong Uplift, Tarim Basin, China. Petroleum Science, 8(4):382-391
|
|
Luo Q Y, George S C, Xu Y H, Zhong N N. 2016. Organic geochemical characteristics of the Mesoproterozoic Hongshuizhuang Formation from northern China:Implications for thermal maturity and biological sources. Organic Geochemistry, 99:23-37
|
|
田涛, 任战利, 马国福, 张睿胜, 杨智明, 郭科, 董欣. 2014. 雅布赖盆地萨尔台凹陷烃源岩地球化学特征、成熟度演化与油气关系. 地球物理学进展, 29(6):2745-2753
|
|
李素梅, 史权, 张宝收, 张海祖, 潘娜, 赵明, 孟祥兵. 2013a. 用高分辨率质谱揭示塔中4油田原油成因机制. 地球科学——中国地质大学学报, 38(1):94-104
|
|
Altgelt K H, Boduszynski M M. 1993. Composition and Analysis of Heavy Petroleum Fractions. New York:CRC Press
|
|
Hughey C A, Galasso S A, Zumberge J E. 2007. Detailed compositional comparison of acidic NSO compounds in biodegraded reservoir and surface crude oils by negative ion electrospray Fourier transform ion cyclotron resonance mass spectrometry. Fuel, 86(5-6):758-768
|
|
Luo Q Y, Qu Y S, Chen Q, Xiong Z R. 2017. Organic geochemistry and petrology of mudrocks from the upper carboniferous batamayineishan formation, Wulungu Area, Junggar Basin, China:Implications for petroleum exploration. Energy & Fuels, 31(10):10628-10638
|
|
万中华, 李素梅, 王政军, 任苗颂, 张红臣, 孟祥兵, 孙爱艳. 2015. 南堡凹陷原油高分辨质谱特征及其地球化学意义. 地球科学——中国地质大学学报, 40(11):1834-1845
|
|
Chakhmakhchev A, Suzuki N. 1995. Saturate biomarkers and aromatic sulfur compounds in oils and condensates from different source rock lithologies of Kazakhstan, Japan and Russia. Organic Geochemistry, 23(4):289-299
|
|
Shi Q, Pan N, Long H Y, Cui D C, Guo X F, Long Y H, Chung K H, Zhao S Q, Xu C M, Hsu C S. 2013. Characterization of middle-temperature gasification coal tar. Part 3:Molecular composition of acidic compounds. Energy & Fuels, 27(1):108-117
|
|
王培荣, 赵红, 朱翠山, 张大江, 徐冠军, 宋孚庆, 王汇彤. 2004. 非烃地球化学及其应用概述. 沉积学报, 22(S1):98-105
|
|
Stanford L A, Rodgers R P, Marshall A G, Czarnecki J, Wu X A, Taylor S. 2007. Detailed elemental compositions of emulsion interfacial material versus parent oil for nine geographically distinct light, medium, and heavy crude oils, detected by negative-and positive-ion electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry. Energy & Fuels, 21(2):973-981
|
|
Hughey C A, Rodgers R P, Marshall A G, Qian K N, Robbins W K. 2002. Identification of acidic NSO compounds in crude oils of different geochemical origins by negative ion electrospray Fourier transform ion cyclotron resonance mass spectrometry. Organic Geochemistry, 33(7):743-759
|
|
Liu P, Xu C M, Shi Q, Pan N, Zhang Y H, Zhao S Q, Chung K H. 2010. Characterization of sulfide compounds in petroleum:selective oxidation followed by positive-ion electrospray Fourier transform ion cyclotron resonance mass spectrometry. Analytical Chemistry, 82(15):6601-6606
|
|
史权, 侯读杰, 陆小泉, 周寅驰, 赵锁奇. 2007. 负离子电喷雾-傅里叶变换离子回旋共振质谱分析辽河原油中的环烷酸. 分析测试学报, 26(S1):317-320
|
|
张春明, 姜在兴, 郭英海, 张维生. 2013. 川东南-黔北地区龙马溪组地球化学特征与古环境恢复. 地质科技情报, 32(2):124-129
|
|
Kendick E. 1963. A mass scale based on CH2=14.0000 for high resolution mass spectrometry of organic compounds. Analytical Chemistry, 35(13):2146-2154
|
|
程顶胜, 窦立荣, 万仑坤, 史权. 2010. 应用高分辨率质谱分析苏丹高酸值原油成因. 岩石学报, 26(4):1303-1312
|
|
张道光. 2015. 川东南武隆地区五峰-龙马溪组富有机质页岩特征. 硕士学位论文. 成都:成都理工大学
|
|
|
|
