Scaling Behavior of Surficial Geochemical Reactions
LIU Yuan-yuan1, MA Teng-fei1, CHEN Yang1, YANG Xiao-fan2, LIU Chong-xuan3
1. MOE Key Laboratory of Surficial Geochemistry, School of Earth Sciences and Engineering, Nanjing University,Nanjing 210023, China; 2. Faculty of Geographical Science, Beijing Normal University,Beijing 100875, China; 3. School of Environmental Science and Engineering, Southern University of Science and Technology, Shenzhen Guangdong 518055, China
Abstract：The geochemical reaction rate in the supergene environment has a significant scale effect. The field observation rate of many geochemical reactions is 2 to 5 orders of magnitude lower than the laboratory observation rate, which makes the comparison and extrapolation of research results at different scales extremely difficult. This article summarizes the influencing factors of the geochemical reaction rate changes with temporal and spatial scales, emphasizes the main controlling process of the geochemical reaction rate changes with the scale, as well as the scale effect caused by sub-scale heterogeneity. Finally, several research methods of scale conversion are introduced. Since the scale effect of the geochemical reaction rate is widespread, it is necessary to understand its limitations and select an appropriate extrapolation method when the geochemical reaction rate is extrapolated.
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